关键词:
Chemical industry
摘要:
Driven by global carbon neutrality initiatives and the development of circular economy, bio-based materials are gradually emerging as significant alternatives to petroleum-based counterparts. Among these, 2,5-furandicarboxylic acid (FDCA), with its rigid aromatic ring structure and exceptional physicochemical properties, is recognized as the most promising bio-based substitute for terephthalic acid, demonstrating broad application prospects in sustainable polymer materials. This review systematically analyzes mainstream FDCA production processes (including HMF, MMF/RMF, glucaric acid, and furfural/furoic acid routes), compares their economic viability and environmental benefits, and identifies the HMF pathway as the most industrially feasible approach currently available. However, key challenges persist, including poor stability of intermediate HMF, high energy consumption in separation processes, and limitations in catalytic system selectivity. By systematically organizing the technological routes, key steps, and industrialization processes of FDCA production through chemical methods, this study aims to provide theoretical references and technical support for promoting the efficient development and industrial upgrading of the FDCA sector. In the future, by focusing on high-value-added markets, developing novel HMF derivatization processes, advancing integrated chain production, and coordinating policies with industrial chain synergies, there is potential to overcome cost constraints and accelerate the industrialization process of FDCA. © 2025 Chemical Industry Press Co., Ltd.. All rights reserved.