关键词:
Amorphous semiconductors
Elemental semiconductors
Germanium
Electrical properties
Sputter deposition
摘要:
Hydrogenated amorphous germanium‐nitrogen alloys (a‐GeN x :H) were synthesized as a new group of amorphous semiconductors by rf(13.56 MHz) reactive sputtering of a Ge target in a gas mixture of Ar+N2+H2 under a variety of deposition conditions such as gas ratio, rf‐discharge power, and substrate temperature. Structural, optical, and electrical properties of those a‐GeN x :H alloys were systematically measured and are discussed in relation to their preparation conditions. The optical band gapE 0 4 of a‐GeN x :H alloys could be continuously controlled in the range from 1.1 eV to 3.3 eV primarily depending on the atomic N/Ge ratio in the film. The role of hydrogen and nitrogen in the optical and electrical properties of the material is also crucially demonstrated.