关键词:
Titanium alloys
摘要:
To improve alloy properties and the distribution level of TiB2 particles in the alloy matrix, mechanical alloying was used to prepare the Cu-TiB2 alloy. But even after long-time ball milling, the in situ reaction between Cu-B and Cu-Ti alloy powders still cannot be observed in the whole process. The kinetics of the in situ reaction during high-temperature heat treatment was first investigated and led to the following results. With the increase of heat-treatment time t or diffusion depth X, both the moving speed Delta x/Delta t of reaction front edge and nucleation rate Z(x) of TiB2 particles decrease at a fast rate and finally stabilize at a very low level. The falling rate of moving speed Delta x/Delta t increases with the decrease of temperature. Although the C-Ti' value of the Ti element gives a poor effect on the moving speed Delta x/Delta t, it significantly affects the nucleation rate of TiB2 particles, and its falling rate increases with a decreasing C-Ti' value. And for the same diffusion depth X and C-Ti', the nucleation rate of TiB2 decreases with increasing the heat-treatment temperature. These results were verified by the microstructure change after the heat treatments at temperatures of 773 K, 973 K, and 1173 K (500 degrees C, 700 degrees C, and 900 degrees C), respectively. Finally, the best combination of ball-milling and heat-treatment conditions was obtained. (C) The Minerals, Metals & Materials Society and ASM International 2015